Sintesis Metil Ester Sulfonat Berbasis Minyak Biji Kelor (Moringa Oliofera L.) pada Variasi Waktu dan Suhu Sulfonasi
DOI:
https://doi.org/10.23887/jstundiksha.v12i2.50380Keywords:
Methyl ester sulfonate, Moringa seeds oil, sulfonation, NaHSO3 , CaOAbstract
Penggunaan surfaktan sintetis berbasis petrokimia memiliki efek negatif pada kesehatan manusia dan lingkungan karena bersifat korosif dan beracun, menyebabkan pemanasan global, dan kelangkaan sumber daya fosil. Metil ester sulfonat (MES) merupakan salah satu jenis surfaktan anionik yang banyak diaplikasikan dalam berbagai industri. Bahan baku pembuatan surfaktan berasal dari minyak bumi yang tidak dapat diperbaharui dan tidak ramah lingkungan, sehingga diperlukan bahan baku alternatif lain yaitu dari minyak biji kelor. Penelitian ini bertujuan untuk mensintesis MES dari minyak biji kelor (Moringa oliofera L.) pada variasi suhu (70, 80, dan 90) 0C dan waktu reaksi (3, 4 dan 5) jam, serta mengkarakterisasi MES menggunakan spektrofotometer FTIR pada kondisi optimum. Jenis penelitian ini adalah penelitian eksperimental laboratorium. Hasil penelitian menunjukkan bahwa MES dapat sintesis dari minyak biji kelor pada kondisi optimum suhu 80 0C dan waktu reaksi 4 jam. Produk MES berwarna putih kekuningan, pH 7 dan yield 66,72 %. Karakterisasi FTIR menunjukkan pita serapan S=O sulfonat yang menandakan terbentuknya produk MES.
References
Alfauziah, F. V., Mardhiyah, F. J., Nadia, A., & Wijaya, K. (2020). Synthesis of Coconut Oil-based Sodium Methyl Ester Sulfonate for the Application of Enhanced Oil Recovery. Journal of the Indonesian Chemical Society, 3(1), 59. https://doi.org/10.34311/jics.2020.03.1.68.
Alwadani, N., & Fatehi, P. (2018). Synthetic and Lignin-based Surfactants: Challenges and Opportunities. Carbon Resources Conversion, 1(2), 126–138. https://doi.org/10.1016/j.crcon.2018.07.006.
Amaliah, D., Qadariyah, L., & Mahfud, M. (2021). The Production of Surfactant Anionic Methyl Ester Sulfonate (MES) from Virgin Coconut Oil (VCO) with Ultrasound-Assisted. Journal of Physics: Conference Series, 1845(1). https://doi.org/10.1088/1742-6596/1845/1/012005.
Azis, M. A. ., Triwahyono, S., Jalil, A. ., Rapai, H. A. ., & Atabani, A. . (2016). Transesterification of Moringa Oleifera Oil to Biodiesel Over Potassium Flouride Loaded on Eggshell Catalyst. Malaysian Journal of Catalysis, 1, 22–26. https://mjcat.utm.my.
Bhutada, P. R., Jadhav, A. J., Pinjari, D. V., Nemade, P. R., & Jain, R. D. (2016). Solvent Assisted Extraction of Oil from Moringa oleifera Lam. Seeds. Industrial Crops and Products, 82, 74–80. https://doi.org/10.1016/j.indcrop.2015.12.004.
Chalim, A., Wibowo, A. A., Suryandari, A. S., Syarifuddin, M. M., & Tohir, M. (2017). Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk. Jurnal Teknik Kimia Dan Lingkungan, 1(1), 28. https://doi.org/10.33795/jtkl.v1i1.23.
Dominguez, Y. D., Garcia, D. T., Perez, L. G., Fernandez-Santana, E., MacIas, M. R., Fischer, T., & Piloto-Rodriguez, R. (2019). Rheological Behavior and Properties of Biodiesel and Vegetable Oil from Moringo oleifera Lam. Afinidad, 76(587), 204–212.
Esmaeili, H., Yeganeh, G., & Esmaeilzadeh, F. (2019). Optimization of Biodiesel Production from Moringa oleifera Seeds Oil in The Presence of Nano-MgO Using Taguchi Method. International Nano Letters, 9(3), 257–263. https://doi.org/10.1007/s40089-019-0278-2.
Fu, X., Su, J., Hou, L., Zhu, P., Hou, Y., Zhang, K., Li, H., Liu, X., Jia, C., & Xu, J. (2021). Physicochemical and Thermal Characteristics of Moringa oleifera Seed Oil. Advanced Composites and Hybrid Materials, 4(3), 685–695. https://doi.org/10.1007/s42114-021-00302-4.
Hariani, P. L., Riyanti, F., & Fadilah, A. (2016). The Influence of Time Reaction to Characteristic of Methyl Ester Sulfonate from Seed Oil ketapang. Indonesian Journal of Fundamental and Applied Chemistry, 1(1), 14–18. https://doi.org/10.24845/ijfac.v1.i1.14.
Iman, N., Razak, A. R., & Nurhaeni, N. (2016). Sintesis Surfaktan Metil Ester Sulfonat (Mes) dari Metil Laurat. Kovalen, 2(2), 54–66. https://doi.org/10.22487/j24775398.2016.v2.i2.6726.
Jaksen, Silviyati, I., Supraptiah, E., & Daniar, Rima Margaretty, E. (2020). Effect of Sulfonation Temperature and Time on the Preparation of Methyl Ester Sulfonate Surfactant From Crude Palm Oil (CPO) Based Methyl Ester. Proceedings of the 4th Forum in Research, Science, and Technology, 7(1), 95–102. https://doi.org/https://dx.doi.org/10.2991/ahe.k.210205.018.
Kesic, Z., Lukic, I., Zdujic, M., Mojovic, L., & Skala, D. (2016). Calcium Oxide Based Catalysts for Biodiesel Production: A Review. Chemical Industry and Chemical Engineering Quarterly, 22(4), 391–408. https://doi.org/10.2298/CICEQ160203010K.
Niju, S., Anushya, C., & Balajii, M. (2018). Process Optimization for Biodiesel Production from Moringa oleifera Oil Using Conch Shells as Heterogeneous Catalyst. Environmental Progress and Sustainable Energy, 38(3), 1–12. https://doi.org/10.1002/ep.13015.
Niju, S., Balajii, M., & Anushya, C. (2019). A Comprehensive Review on Biodiesel Production Using Moringa oleifera Oil. International Journal of Green Energy, 16(9), 702–715. https://doi.org/10.1080/15435075.2019.1619565.
Nurliana, L., Kadidae, L. O., Sunarti, S., & Musta, R. (2021). Characterization of Methyl Ester Sulfonate (MES) from Mahagony (Swietenia macrophylla King) with Variations in H2SO4 Concentration and Sulfonation Duration. ALCHEMY Jurnal Penelitian Kimia, 17(2), 192. https://doi.org/10.20961/alchemy.17.2.51613.192-201.
Omonhinmin, C., Olomukoro, E., Ayoola, A., & Egwim, E. (2020). Utilization of Moringa oleifera Oil for Biodiesel Production: A Systematic Review. AIMS Energy, 8(1), 102–121. https://doi.org/10.3934/ENERGY.2020.1.102.
Qadariyah, L., Sahila, S., & Mahfud, M. (2021). The Effect of Reaction Time and Temperature on The Synthesis of Methyl Ester Sulfonate Surfactant from Palm Oil as A Feedstock Using Microwave-Assisted heating. ASEAN Journal of Chemical Engineering, 21(1), 104–112. https://doi.org/10.22146/ajche.63786.
Qadariyah, L., Sahila, S., Sirait, C., Purba, C. P. E., Bhuana, D. S., & Mahfud, M. (2022). Surfactant Production of Methyl Ester Sulfonate from Virgin Coconut Oil using Aluminum Oxide with Microwave Assistance. International Journal of Technology, 13(2), 378–388. https://doi.org/10.14716/ijtech.v13i2.4449.
Rashed, M. M., Masjuki, H. H., Kalam, M. A., Alabdulkarem, A., Rahman, M. M., Imdadul, H. K., & Rashedul, H. K. (2016). Study of The Oxidation Stability and Exhaust Emission Analysis of Moringa olifera Biodiesel in A Multi-Cylinder Diesel Engine with Aromatic Amine Antioxidants. Renewable Energy, 94, 294–303. https://doi.org/10.1016/j.renene.2016.03.043.
Sahila, S., Qadariyah, L., & Mahfud, M. (2021). The Study on Factors Affecting the Synthesis of Methyl Ester Sulfonate from Palm Oil using CaO Catalyst with Microwave-Assisted. Journal of Physics: Conference Series, 1845(1). https://doi.org/10.1088/1742-6596/1845/1/012004.
Salimi, Y. K., Ischak, N. I., & Ibrahim, Y. (2019). Karakterisasi Asam Lemak Hasil Hidrolisis pada Minyak Biji Kelor (Moringa oleifera) dengan Metode Kromatografi Gas-Spektroskopi Massa. Jambura Journal of Chemistry, 1(1), 6–14. https://doi.org/10.34312/jambchem.v1i1.2101.
Siti Afida, I., Razmah, G., & Zulina, A. M. (2016). Biodegradation of Various Homologues of Palm-Based Methyl Ester Sulphonates (MES). Sains Malaysiana, 45(6), 949–954.
Slamet, Ibadurrohman, M., & Wulandari, P. P. (2017). Synthesis of Methyl Ester Sulfonate Surfactant from Crude Palm Oil as an Active Substance of Laundry Liquid Detergent. AIP Conference Proceedings, 1904. https://doi.org/10.1063/1.5011915.
Soy, R. C., Kipkemboi, P. K., & Rop, K. (2020). Synthesis, Characterization, and Evaluation of Solution Properties of Sesame Fatty Methyl Ester Sulfonate Surfactant. ACS Omega, 5(44), 28643–28655. https://doi.org/10.1021/acsomega.0c03698.
Wardoyo, A., & Daniel. (2017). Sintesis Etilendiamida dari Metil Ester Minyak Biji Bintaro (Cerbera manghas, L.) Melalui Reaksi Amidasi Dengan Katalis NaOCH3. Kimia, 247–254.
Yuliatmi, Bahri, S., & Yelmida. (2019). Sintesis Surfaktan Metil Ester Sulfonat (MES) dari Palm Oil Metyhl Eter (POME) dan Natrium Bisulfit (NaHSO3) dengan Variasi Suhu Sulfonasi dan Rasio Mol POME : NaHSO3. Journal of Chemical Information and Modeling, 6, 1–7.
Yusuff, A. S., Porwal, J., Bhonsle, A. K., Rawat, N., & Atray, N. (2021). Valorization of Used Cooking Oil as A Source of Anionic Surfactant Fatty Acid Methyl Ester Sulfonate: Process Optimization and Characterization Studies. Biomass Conversion and Biorefinery, 0123456789. https://doi.org/10.1007/s13399-021-01663-y.
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