Efek Tekanan Spray terhadap Sifat Optik dan Listrik Film Tipis ZnO:Mg dengan Metode Microwave Assisted Spray Pyrolysis

Authors

  • Sulhadi Universitas Negeri Semarang, Semarang, Indonesia
  • Siti Hidayatur Rofi'ah Universitas Negeri Semarang, Semarang, Indonesia
  • Siti Wahyuni Universitas Negeri Semarang, Semarang, Indonesia
  • Muqoyyanah Badan Riset dan Inovasi Nasional (BRIN), Tangerang Selatan, Banten, Indonesia
  • Putut Marwoto Badan Riset dan Inovasi Nasional (BRIN), Tangerang Selatan, Banten, Indonesia

DOI:

https://doi.org/10.23887/jstundiksha.v13i2.81644

Keywords:

Film Tipis, Microwave Assisted Spray Pyrolysis, Tekanan

Abstract

Fabrikasi film tipis di atas substrat kaca yang homogen dengan sifat optik dan listrik yang unggul masih menjadi tantangan. Oleh sebab itu, pemilihan metode serta parameter fabrikasi menjadi hal yang penting untuk diteliti. Pada penelitian ini, film tipis ZnO doping Mg (ZnO:Mg) difabrikasi pada substrat kaca menggunakan metode Microwave Assisted Spray Pyrolysis dengan memvariasikan tekanan spray nitrogen, yaitu sebesar 1,4; 2,1; 2,8; 3,5; dan 4,2 kg/cm2. Film tipis yang telah difabrikasi kemudian diuji dengan UV-Vis dan IV-meter untuk menganalisis sifat optik dan listriknya. Hasil penelitian menunjukkan bahwa tekanan spray memiliki pengaruh signifikan terhadap karakteristik optik dan listrik dari film tipis ZnO, Dengan peningkatan tekanan spray, film tipis yang dihasilkan cenderung memiliki ketebalan yang lebih seragam, yang berkontribusi pada peningkatan transparansi optik dan penurunan nilai resistivitas listrik. Metode penelitian yang digunakan adalah deskriptif kuantitatif. Penelitian ini bertujuan. Dalam penelitian ini, sampel yang digunakan adalah film tipis ZnO (seng oksida yang didoping dengan magnesium). Tujuan dari penelitian ini adalah untuk mengeksplorasi dan memahami pengaruh variasi tekanan spray pada proses sintesis terhadap sifat optik dan listrik dari film tipis ZnO yang dihasilkan menggunakan metode Microwave Assisted Spray Pyrolysis (MASP). Implikasi penelitian ini adalah penelitian ini memberikan wawasan baru tentang bagaimana parameter proses sintesis dapat diatur untuk mengoptimalkan kinerja material. Temuan ini mengindikasikan bahwa dengan pengaturan tekanan spray yang tepat, film tipis ZnO.

References

Benali, H., Hartiti, B., Lmai, F., Batan, A., Fadili, S., & Thevenin, P. (2022). Synthesis And Characterization Of Mg-Doped Zno Thin-Films For Photovoltaic Applications. Materials Today: Proceedings, 66(23), 212–216. https://doi.org/10.1016/j.matpr.2022.04.490. DOI: https://doi.org/10.1016/j.matpr.2022.04.490

Bouachiba, Y., Mammeri, A. B. D. E. L. O. U. A. D. O. U. D., Bouabellou, A., Rabia, O., Saidi, S., Taabouche, A., & Boudissa, M. (2021). Optoelectronic And Birefringence Properties Of Weakly Mg-Doped Zno Thin Films Prepared By Spray Pyrolysis. Journal Of Materials Science: Materials In Electronics, 33(9), 6689–6699. https://doi.org/10.1007/s10854-022-07844-3. DOI: https://doi.org/10.1007/s10854-022-07844-3

Bright, C. I. (2018). Transparent Conductive Thin Films. Optical Thin Films And Coatings, 24(25), 741–788. https://doi.org/10.1016/b978-0-08-102073-9.00021-7. DOI: https://doi.org/10.1016/B978-0-08-102073-9.00021-7

El-Bashir, S. M., Alharbi, O. A., & Alsalhi, M. S. (2019). Thin-Film Lscs Based On Pmma Nanohybrid Coatings: Device Optimization And Outdoor Performance. International Journal Of Photoenergy, 24(26), 190. https://doi.org/10.1155/2013/235875. DOI: https://doi.org/10.1155/2013/235875

Etacheri, V., Roshan, R., & Kumar, V. (2017). Mg-Doped Zno Nanoparticles For Efficient Sunlight-Driven Photocatalysis. Acs Applied Materials & Interfaces, 4(5), 2717–2725. https://doi.org/10.1021/am300359h. DOI: https://doi.org/10.1021/am300359h

Fang, V., Kennedy, J. V, Futter, J., & Manning, J. (2014). A Review Of Near Infrared Reflectance Properties Of Metal Oxide Nanostructures. Gns Science, 2(21), 100. https://api.semanticscholar.org/corpusid:17554713.

Foo, K. L., Kashif, M., Hashim, U., & Liu, W. W. (2019). Effect Of Different Solvents On The Structural And Optical Properties Of Zinc Oxide Thin Films For Optoelectronic Applications. Ceramics International, 40(1 Part A), 753–761. https://doi.org/10.1016/j.ceramint.2013.06.065. DOI: https://doi.org/10.1016/j.ceramint.2013.06.065

Hallani, G. E., Nasih, S., Fazouan, N., Liba, A., Khuili, M., Sajieddine, M., & Atmani, E. H. (2017). Comparative Study For Highly Al And Mg Doped Zno Thin Films Elaborated By Sol Gel Method For Photovoltaic Application. Journal Of Applied Physics, 121(13), 50. https://doi.org/10.1063/1.4979724. DOI: https://doi.org/10.1063/1.4979724

Jeng, J. S., & Wu, C. M. (2019). Fabrication Of Solution-Processed Nitrogen-Doped Niobium Zinc Tin Oxide Thin Film Transistors Using Ethanolamine Additives. Journal Of Alloys And Compounds, 729(2), 370–378. https://doi.org/10.1016/j.jallcom.2017.09.151. DOI: https://doi.org/10.1016/j.jallcom.2017.09.151

Karthick, P., Vijayanarayanan, D., Sridharan, M., Rt, A. K., Sanjeeviraja, C., & Jeyadheepan, K. (2020). Optimization Of Substrate Temperature And Characterization Of Tin Oxide Based Transparent Conducting Thin Films For Application In Dye-Sensitized Solar Cells. Thin Solid Films, 631, 1–11. https://doi.org/10.1016/j.tsf.2017.04.003. DOI: https://doi.org/10.1016/j.tsf.2017.04.003

Kathalingam, A., Valanarasu, S., Ahamad, T., Alshehri, S. M., & Kim, H. S. (2020). Spray Pressure Variation Effect On The Properties Of Cds Thin Films For Photodetector Applications. Ceramics International, 47(6), 7608–7616. https://doi.org/10.1016/j.ceramint.2020.11.100. DOI: https://doi.org/10.1016/j.ceramint.2020.11.100

Kim, G. H., Shin, E. A., Jung, J. Y., Lee, J. Y., & Lee, C. K. (2020). Effect Of Spray Parameters On Electrical Characteristics Of Printed Layer By Morphological Study. Processes, 10(5), 999. https://doi.org/10.3390/pr10050999. DOI: https://doi.org/10.3390/pr10050999

Lee, P., Gaige, T., & Hung, P. (2023). Microfluidic Systems For Live Cell Imaging. Methods In Cell Biology, 102(78), 77–103. https://doi.org/10.1016/b978-0-12-374912-3.00004-3. DOI: https://doi.org/10.1016/B978-0-12-374912-3.00004-3

Malyi, O. I., Yeung, M. T., Poeppelmeier, K. R., Persson, C., & Zunger, A. (2019). Spontaneous Non-Stoichiometry And Ordering In Degenerate But Gapped Transparent Conductors. Matter, 1(1), 280–294. https://doi.org/10.1016/j.matt.2019.05.014. DOI: https://doi.org/10.1016/j.matt.2019.05.014

Marangoni, J. A., & Costa Ferreira, M. (2020). Influence Of Working Pressure And Spray Nozzle On The Distribution Of Spray Liquid In Manual Backpack Sprayers. Arquivos Do Instituto Biológico, 86(24), 442018. https://doi.org/10.1590/1808-1657000442018. DOI: https://doi.org/10.1590/1808-1657000442018

Muchuweni, E., Sathiaraj, T. S., & Nyakotyo, H. (2022). Effect Of Annealing On The Microstructural, Optical And Electrical Properties Of Zno Nanowires By Hydrothermal Synthesis For Transparent Electrode Fabrication. Materials Science And Engineering: B, 227(24), 68–73. https://doi.org/10.1016/j.mseb.2017.10.006. DOI: https://doi.org/10.1016/j.mseb.2017.10.006

Pak, M. N., Kim, S. C., Sin, S. I., Kim, K. C., & Pak, S. S. (2020). Research On The Ultrasonic Driving Circuit Of Music Rhythm Driven Method To Suppress The Noise Of Ultrasonic Cleaner. Applied Acoustics, 195(20), 108845. https://doi.org/10.1016/j.apacoust.2022.108845. DOI: https://doi.org/10.1016/j.apacoust.2022.108845

Prabu, R. D., Valanarasu, S., Ganesh, V., Shkir, M., Kathalingam, A., & Alfaify, S. (2018). Effect Of Spray Pressure On Optical, Electrical And Solar Cell Efficiency Of Novel Cu2o Thin Films. Surface And Coatings Technology, 347(25), 164–172. https://doi.org/10.1016/j.surfcoat.2018.04.084. DOI: https://doi.org/10.1016/j.surfcoat.2018.04.084

Schoonheydt, R. A., & Johnston, C. T. (2020). Surface And Interface Chemistry Of Clay Minerals. Developments In Clay Science Elseveir, 5(23), 139–172. https://doi.org/10.1016/b978-0-08-098258-8.00005-5. DOI: https://doi.org/10.1016/B978-0-08-098258-8.00005-5

Singh, S. K., Hazra, P., Tripathi, S., & Chakrabarti, P. (2016). Optical Characterization Of Mg-Doped Zno Thin Films Deposited By Rf Magnetron Sputtering Technique. Aip Conference Proceedings, 1728(1), 20168. https://doi.org/10.1063/1.4946219. DOI: https://doi.org/10.1063/1.4946219

Soni, M., K., S., & Sharma, S. K. (2019). Influence Of Nitrogen Partial Pressure On Optical Properties Of Magnetron Sputtered Al-Si-N Thin Films. Thin Solid Films, 682(24), 1–9. https://doi.org/10.1016/j.tsf.2019.05.006. DOI: https://doi.org/10.1016/j.tsf.2019.05.006

Tran, T. N. A., Tran, T. H., Nguyen, V. T., & Pham, N. H. (2019). Characteristics Of Ag-Doped Zno Thin Films Prepared By Sputtering Method. Vnu Journal Of Science: Mathematics-Physics, 35(4), 13. https://doi.org/10.25073/2588-1124/vnumap.4365. DOI: https://doi.org/10.25073/2588-1124/vnumap.4365

Tsay, C. Y., Fan, K. S., Wang, Y. W., Chang, C. J., Tseng, Y. K., & Lin, C. K. (2021). Transparent Semiconductor Zinc Oxide Thin Films Deposited On Glass Substrates By Sol-Gel Process. Ceramics International, 36(6), 1791–1795. https://doi.org/10.1016/j.ceramint.2010.03.005. DOI: https://doi.org/10.1016/j.ceramint.2010.03.005

Volkova, M. G., Storozhenko, V. Y., Petrov, V. V, & Bayan, E. M. (2021). Structural Properties Of Tio2-Sno2 Thin Films Prepared By New Pyrolysis Solid-Phase Method. Journal Of Physics: Conference Series (Vol, 1(1), 12042. https://doi.org/10.1088/1742-6596/2086/1/012042. DOI: https://doi.org/10.1088/1742-6596/2086/1/012042

Zak, A. K., Majid, W. A., Darroudi, M., & Yousefi, R. (2011). Synthesis And Characterization Of Zno Nanoparticles Prepared In Gelatin Media. Materials Letters, 65(1), 70–73. https://doi.org/10.1016/j.matlet.2010.09.029. DOI: https://doi.org/10.1016/j.matlet.2010.09.029

Zhang, J., Dong, P., Gao, Y., Sheng, C., & Li, X. (2016). Performance Enhancement Of Zito Thin-Film Transistors Via Graphene Bridge Layer By Sol-Gel Combustion Process. Acs Applied Materials And Interfaces, 7(43), 24103–24109. https://doi.org/10.1021/acsami.5b07148. DOI: https://doi.org/10.1021/acsami.5b07148

Zhang, K. H., Xi, K., Blamire, M. G., & Egdell, R. G. (2021). P-Type Transparent Conducting Oxides. Journal Of Physics: Condensed Matter, 28(38), 38. https://doi.org/10.1088/0953-8984/28/38/383002. DOI: https://doi.org/10.1088/0953-8984/28/38/383002

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Published

2024-07-25

How to Cite

Sulhadi, Rofi’ah, S. H., Wahyuni, S., Muqoyyanah, & Marwoto, P. (2024). Efek Tekanan Spray terhadap Sifat Optik dan Listrik Film Tipis ZnO:Mg dengan Metode Microwave Assisted Spray Pyrolysis. JST (Jurnal Sains Dan Teknologi), 13(2), 307–316. https://doi.org/10.23887/jstundiksha.v13i2.81644

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Vol. 13 No. 2 (2024): July

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