Kinerja Adsorben Zeolit untuk Meningkatkan Kualitas Air Kolong Bekas Tambang Timah

Penulis

  • Fifia Zulti Pusat Riset Limnologi dan Sumber Daya Air, Badan Riset dan Inovasi Nasional, Bogor, Indonesia

DOI:

https://doi.org/10.23887/jstundiksha.v12i2.44129

Kata Kunci:

adsorpsi, zeolit, warna, kekeruhan

Abstrak

Kolam bekas penambangan timah sangat melimpah di pulau Bangka dan berpotensi untuk dijadikan sebagai sumber air baku dengan pengolahan terlebih dahulu. Zeolit telah banyak digunakan dalam pengolahan air karena kemampuannya yang memadai sebagai adsorben. Penelitian ini bertujuan untuk memanfaatkan dan meningkatkan kinerja zeolit alam untuk menjernihkan air kolong dengan mengukur parameter konsentrasi warna, kekeruhan, pH dan logam Fe. Aktivasi zeolit alam dilakukan dengan pemanasan pada suhu 300 dan 500oC serta perendaman dalam asam sulfat 2M. Air kolong yang diuji dengan  metode batch adsorption untuk melihat kinerja adsorpsi zeolit. Hasil analisa warna dan kekeruhan dengan menggunakan spektrofotometer portable tipe HACH DR/2010 menunjukkan efisiensi reduksi pada kondisi optimum untuk warna sebesar 94,23% dan kekeruhan sebesar 73,33%. Jadi zeolit alam teraktivasi mampu meningkatkan kualitas air kolong dengan menurunkan konsentrasi warna, kekeruhan dan logam besi menjadi 4 PtCo, 3 NTU dan 0,19 mg/L. Nilai ketiga parameter tersebut telah memenuhi standar baku mutu air minum. Simpulan penelitian menunjukkan zeolit alam yang diaktivasi secara fisika-kimia dapat memperbaiki kualitas air kolong.

Referensi

Ahmed, M., Mavukkandy, M. O., Giwa, A., Elektorowicz, M., Katsou, E., Khelifi, O., Naddeo, V., & Hasan, S. W. (2022). Recent developments in hazardous pollutants removal from wastewater and water reuse within a circular economy. Npj Clean Water, 5(1), 12. https://doi.org/10.1038/s41545-022-00154-5.

Aldila, H., Fabiani, V. A., & Dalimunthe, D. Y. (2021). The effect of deproteinization temperature on chitosan extraction for iron metal ions adsorption: Case study in Bangka post tin mining water. Journal of Physics: Conference Series, 1869(1), 1-5. https://doi.org/10.1088/1742-6596/1869/1/012105.

Ali, F., Lestari, D. L., & Putri, M. D. (2019). Application of Ozone Plasma Technology for Treating Peat Water into Drinking Water. IOP Conference Series: Earth and Environmental Science, 385(1), 1-6. https://doi.org/10.1088/1755-1315/385/1/012056.

Asmarhansyah, Badayos, Rodrigo, Sanchez, P., C Sta Cruz, P., & M Florece, L. (2017). Land suitability evaluation of abandoned tin-mining areas for agricultural development in Bangka Island, Indonesia. Journal of Degraded and Mining Lands Management, 04(04), 907–918. https://doi.org/10.15243/jdmlm.2017.044.907.

Astuti, D. W., Mudasir, & Aprilita, N. H. (2019). Preparation and characterization adsorbent based on zeolite from Klaten, Central Java, Indonesia. Journal of Physics: Conference Series, 1156(1), 5–11. https://doi.org/10.1088/1742-6596/1156/1/012002.

Belova, T. P. (2019). Adsorption of heavy metal ions (Cu2+, Ni2+, Co2+ and Fe2+) from aqueous solutions by natural zeolite. Heliyon, 5(9), 1-6. https://doi.org/10.1016/j.heliyon.2019.e02320.

Chalchisa, D., Megersa, M., & Beyene, A. (2018). Assessment of the quality of drinking water in storage tanks and its implication on the safety of urban water supply in developing countries. Environmental Systems Research, 6(1), 12. https://doi.org/10.1186/s40068-017-0089-2.

Cruz, D., Pimentel, M., Russo, A., & Cabral, W. (2020). Charge Neutralization Mechanism Efficiency in Water with High Color Turbidity Ratio Using Aluminium Sulfate and Flocculation Index. Water, 12(2), 572. https://doi.org/10.3390/w12020572.

Farida Hanum, Rikardo Jgst Gultom, & Maradona Simanjuntak. (2017). Adsorpsi zat warna metilen biru dengan karbon aktif dari kulit durian menggunakan koh dan naoh sebagai aktivator. Jurnal Teknik Kimia USU, 6(1), 49–55. https://doi.org/10.32734/jtk.v6i1.1565.

Hammood, Z. A., Chyad, T. F., & Al-Saedi, R. (2021). Adsorption Performance of Dyes over Zeolite for Textile Wastewater Treatment. Ecological Chemistry and Engineering S, 28(3), 329–337. https://doi.org/10.2478/eces-2021-0022.

Jafari, S., Ghorbani-Shahna, F., Bahrami, A., & Kazemian, H. (2018). Adsorptive removal of toluene and carbon tetrachloride from gas phase using Zeolitic Imidazolate Framework-8: Effects of synthesis method, particle size, and pretreatment of the adsorbent. Microporous and Mesoporous Materials, 268, 58–68. https://doi.org/10.1016/j.micromeso.2018.04.013.

Koki, I. B., Md Zain, S., Hin, L. K., Azid, A., Juahir, H., & Abdul Zali, M. (2019). Development of water quality index of ex-mining ponds in Malaysia. Malaysian Journal of Fundamental and Applied Sciences, 15(1), 54–60. https://doi.org/10.11113/mjfas.v15n2019.1079.

Krupskaya, L. T., Golubev, D. A., & Kolobanov, K. A. (2021). Indicators and Factors Resulting in Crisis Phenomena Related to the Environment Hazard of Accumulated Mineral Processing Wastes at Closed Mining Enterprises. IOP Conference Series: Materials Science and Engineering, 1079(7), 1-12. https://doi.org/10.1088/1757-899x/1079/7/072011.

Liliani Rosa, Retnaningdyah, C., & Arisoesilaningsih, E. (2019). Water Quality Evaluation of Post-Tin Mining Ponds Tourism in Bangka Island Using Diatom as Bioindicator. Journal of Indonesian Tourism and Development Studies, 7(1), 39–44. https://doi.org/10.21776/ub.jitode.2019.07.01.06.

Mahmad, M. K. N., Rozainy, M. A. Z. M. R., Abustan, I., & Baharun, N. (2016). Electrocoagulation Process by Using Aluminium and Stainless Steel Electrodes to Treat Total Chromium, Colour and Turbidity. Procedia Chemistry, 19, 681–686. https://doi.org/10.1016/j.proche.2016.03.070.

Makropoulos, C., Rozos, E., Tsoukalas, I., Plevri, A., Karakatsanis, G., Karagiannidis, L., Makri, E., Lioumis, C., Noutsopoulos, C., Mamais, D., Rippis, C., & Lytras, E. (2018). Sewer-mining: A water reuse option supporting circular economy, public service provision and entrepreneurship. Journal of Environmental Management, 216, 285–298. https://doi.org/10.1016/j.jenvman.2017.07.026.

Malik, Q. H. (2018). Performance of alum and assorted coagulants in turbidity removal of muddy water. Applied Water Science, 8(1), 40. https://doi.org/10.1007/s13201-018-0662-5.

Martama, E., & Suwartha, N. (2021). Impacts of zeolite activation temperature and grain size toward bioretention system efficiency in removing Pb and Zn pollutant in stormwater runoff. IOP Conference Series: Earth and Environmental Science, 623(1), 1-6. https://doi.org/10.1088/1755-1315/623/1/012032.

Mierczynski, P., Szkudlarek, L., Chalupka, K., Maniukiewicz, W., Wahono, S. K., Vasilev, K., & Szynkowska-Jozwik, M. I. (2021). The Effect of the Activation Process and Metal Oxide Addition (CaO, MgO, SrO) on the Catalytic and Physicochemical Properties of Natural Zeolite in Transesterification Reaction. Materials, 14(9). https://doi.org/10.3390/ma14092415.

Mohamad Zain, R., Shaari, N., Mohd Amin, M., & Jani, M. (2019). Effect of Zeolite on the Water Quality and Growth Performance of Red Hybrid Tilapia (Oreochromis niloticus). Proceedings of the Proceedings of The 2nd International Conference On Advance And Scientific Innovation, ICASI 2019, 18 July, Banda Aceh, Indonesia. https://doi.org/10.4108/eai.18-7-2019.228848.

Ngapa, Y. D. (2017). Study of The Acid-Base Effect on Zeolite Activation and Its Characterization as Adsorbent of Methylene Blue Dye. JKPK (Jurnal Kimia Dan Pendidikan Kimia), 2(2), 90. https://doi.org/10.20961/jkpk.v2i2.11904.

Nurtjahya, E., Franklin, J., Umroh, & Agustina, F. (2017). The Impact of tin mining in Bangka Belitung and its reclamation studies. MATEC Web of Conferences, 101, 1–6. https://doi.org/10.1051/matecconf/201710104010.

Ojstršek, A., Vouk, P., & Fakin, D. (2022). Adsorption of Pollutants from Colored Wastewaters after Natural Wool Dyeing. Materials, 15(4), 1488. https://doi.org/10.3390/ma15041488.

Onen, V., Beyazyuz, P., & Yel, E. (2018). Removal of Turbidity from Travertine Processing Wastewaters by Coagulants, Flocculants and Natural Materials. Mine Water and the Environment, 37(3), 482–492. https://doi.org/10.1007/s10230-017-0499-4.

Paul, B., Dynes, J. J., & Chang, W. (2017). Modified zeolite adsorbents for the remediation of potash brine-impacted groundwater: Built-in dual functions for desalination and pH neutralization. Desalination, 419, 141–151. https://doi.org/10.1016/j.desal.2017.06.009.

Qasem, N. A. A., Mohammed, R. H., & Lawal, D. U. (2021). Removal of heavy metal ions from wastewater: a comprehensive and critical review. Npj Clean Water, 4(1), 36. https://doi.org/10.1038/s41545-021-00127-0.

Rozumová, L., & Prehradná, J. (2018). Reducing the Content of Metal Ions from Mine Water by Using Converter Sludge. Water, 10(1), 38. https://doi.org/10.3390/w10010038.

Saleh, T. A., Mustaqeem, M., & Khaled, M. (2022). Water treatment technologies in removing heavy metal ions from wastewater: A review. Environmental Nanotechnology, Monitoring & Management, 17. https://doi.org/10.1016/j.enmm.2021.100617.

Sales, F. R. P., Serra, R. B. G., Figueirêdo, G. J. A. de, Hora, P. H. A. da, & Sousa, A. C. de. (2019). Wastewater treatment using adsorption process in column for agricultural purposes. Ambiente e Agua - An Interdisciplinary Journal of Applied Science, 14(1), 1. https://doi.org/10.4136/ambi-agua.2178.

Shaban, M., Abukhadra, M. R., Shahien, M. G., & Khan, A. A. P. (2017). Upgraded modified forms of bituminous coal for the removal of safranin-T dye from aqueous solution. Environmental Science and Pollution Research, 24(22), 18135–18151. https://doi.org/10.1007/s11356-017-9424-4.

Siswoyo, E., Tanjung, D. S., & Jauhari Hamidil Jalaly, M. (2021). Development of Natural Coagulant for Turbidity Removal Created from Marine Product Solid Waste. IOP Conference Series: Earth and Environmental Science, 799(1), 012038. https://doi.org/10.1088/1755-1315/799/1/012038.

Suhartana, S., & Pardoyo, P. (2020). Activation of Natural Zeolite and Its Application for Adsorbents in Domestic Wastewater Treatment in Tembalang District, Semarang City. Jurnal Kimia Sains Dan Aplikasi, 23(1), 28–33. https://doi.org/10.14710/jksa.23.1.28-33.

Suhendi, E., Kurniawan, T., Pradana, A. Y., & Giffari, V. Z. (2021). The Effect of Time on the Activation of Bayah Natural Zeolite for Use in Palm Oil Shell Pyrolysis. Bulletin of Chemical Reaction Engineering & Catalysis, 16(3), 588–600. https://doi.org/10.9767/BCREC.16.3.10313.588-600.

Utami, U. B. L., Susanto, H., & Cahyono, B. (2020). Neutralization Acid Mine Drainage (AMD) using NaOH at PT. Jorong Barutama Grestone, Tanah Laut, South Borneo. IJCA (Indonesian Journal of Chemical Analysis), 3(1), 17–21. https://doi.org/10.20885/ijca.vol3.iss1.art3.

Vera-Puerto, I., Saravia, M., Olave, J., Arias, C., Alarcon, E., & Valdes, H. (2020). Potential application of chilean natural zeolite as a support medium in treatmentwetlands for removing ammonium and phosphate from wastewater. Water (Switzerland), 12(4), 1–15. https://doi.org/10.3390/W12041156.

Yogafanny, E., Yohan, K. O., & Sungkowo, A. (2018). Treatment of brackish groundwater by zeolite filtration in Sumur Tua Wonocolo, Kedewan, Bojonegoro, East Java. IOP Conference Series: Earth and Environmental Science, 212(1), 012014. https://doi.org/10.1088/1755-1315/212/1/012014.

Yusuf, M., Pamungkas, A., Hudatwi, M., & Irvani. (2021). Distribution of Turbidity Values, Total Suspended Solids and Heavy Metals Pb, Cu in Tanah Merah Beach Waters and Semujur Island Waters, Bangka Tengah Regency. IOP Conference Series: Earth and Environmental Science, 750(1). https://doi.org/10.1088/1755-1315/750/1/012038.

Yusuf, Muh, Adibrata, S., Irvani, I., Pamungkas, A., & Hudatwi, M. (2022). Studi Konsentrasi Logam Berat (Pb dan Cu) dari Sumber Lokasi Pertambangan di Perairan Tanah Merah, Bangka Tengah. Buletin Oseanografi Marina, 11(2), 185–192. https://doi.org/10.14710/buloma.v11i2.37976.

Diterbitkan

2023-10-22

Cara Mengutip

Zulti, F. (2023). Kinerja Adsorben Zeolit untuk Meningkatkan Kualitas Air Kolong Bekas Tambang Timah. JST (Jurnal Sains Dan Teknologi), 12(2), 396–402. https://doi.org/10.23887/jstundiksha.v12i2.44129

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